IDENTIFICATION OF THE MATERIAL AND SUPPLIER

• 1. Product identifier

Product name Synonyms

DEOTABS

DEOTABS

• 1. Uses and uses advised against

Uses URINAL DEODORANT

• 1. Details of the supplier of the product

Supplier name: Kitchen & Catering Supplies

Address: 5 / 13 Day Rd, Rockingham WA 6168

Telephone: (08) 9592 2700

Email: kit-cat@southwest.com.au

Website: www.kitchenandcateringsupplies.com.au

• 1. Emergency telephone numbers

Emergency 0414 586 164

HAZARDS IDENTIFICATION

• 1. Classification of the substance or mixture

CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA

Physical Hazards

Not classified as a Physical Hazard

Health Hazards

Serious Eye Damage / Eye Irritation: Category 2A Carcinogenicity: Category 2

Environmental Hazards

Aquatic Toxicity (Chronic): Category 1

• 1. GHS Label elements

Signal word WARNING Pictograms

Hazard statements

H319 H351 H410

Prevention statements

P202 P264 P273 P280

Causes serious eye irritation. Suspected of causing cancer.

Very toxic to aquatic life with long lasting effects.

Do not handle until all safety precautions have been read and understood. Wash thoroughly after handling.

Avoid release to the environment.

Wear protective gloves/protective clothing/eye protection/face protection.

Response statements

P305 + P351 + P338

P308 + P313 P391

Storage statements

P405

Disposal statements

P501

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

IF exposed or concerned: Get medical advice/ attention. Collect spillage.

Store locked up.

Dispose of contents/container in accordance with relevant regulations.

• 1. Other hazards

No information provided.

COMPOSITION/ INFORMATION ON INGREDIENTS

• 1. Substances / Mixtures

Ingredient	CAS Number	EC Number	Content
PARA-DICHLOROBENZENE	106-46-7	203-400-5	>90%
ADDITIVE(S)	–	–	Remainder

FIRST AID MEASURES

• 1. Description of first aid measures

Eye

Inhalation Skin

Ingestion

First aid facilities

If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by a Poisons Information Centre, a doctor, or for at least 15 minutes.

If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.

If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.

For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Eye wash facilities should be available.

• 1. Most important symptoms and effects, both acute and delayed

Suspected of causing cancer. Irritating to the eyes.

• 1. Immediate medical attention and special treatment needed

Treat symptomatically.

FIRE FIGHTING MEASURES

• 1. Extinguishing media

Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.

• 1. Special hazards arising from the substance or mixture

Combustible. May evolve toxic gases (carbon oxides, hydrogen chloride, phosgene, hydrocarbons) when heated to decomposition.

• 1. Advice for firefighters

Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify those downwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.

• 1. Hazchem code

None allocated.

ACCIDENTAL RELEASE MEASURES

• 1. Personal precautions, protective equipment and emergency procedures

Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.

• 1. Environmental precautions

Prevent product from entering drains and waterways.

• 1. Methods of cleaning up

If spilt, collect and reuse where possible.

• 1. Reference to other sections

See Sections 8 and 13 for exposure controls and disposal.

HANDLING AND STORAGE

• 1. Precautions for safe handling

Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.

• 1. Conditions for safe storage, including any incompatibilities

Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not in use.

• 1. Specific end uses

No information provided.

EXPOSURE CONTROLS / PERSONAL PROTECTION

• 1. Control parameters Exposure standards

Ingredient	Reference	TWA		STEL
		ppm	mg/m³	ppm	mg/m³
p-Dichlorobenzene p-Dichlorobenzene	SWA [AUS] SWA [Proposed]	25 2	150 12	50 10	300 60

Biological limits

No biological limit values have been entered for this product.

• 1. Exposure controls Engineering controls

Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposure standard.

PPE

Eye / Face Not required under normal conditions of use.

Hands Wear PVC or rubber gloves.

Body Not required under normal conditions of use.

Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.

PHYSICAL AND CHEMICAL PROPERTIES

• 1. Information on basic physical and chemical properties

Appearance Odour

Flammability Flash point Boiling point Melting point

COLOURED DISCS

CHARACTERISTIC LAVENDER ODOUR COMBUSTIBLE

65.6°C (cc)

173.4°C

53°C

9.1 Information on basic physical and chemical properties

Evaporation rate pH

Vapour density Relative density Solubility (water) Vapour pressure

Upper explosion limit Lower explosion limit Partition coefficient

Autoignition temperature Decomposition temperature Viscosity

Explosive properties Oxidising properties Odour threshold

NOT RELEVANT NOT RELEVANT

5.07 (Air = 1) 1.46 INSOLUBLE

0.4 mm Hg @ 20°C 16 %

2.5 %

NOT AVAILABLE 412.8°C

NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE NOT AVAILABLE

STABILITY AND REACTIVITY

• 1. Reactivity

Carefully review all information provided in sections 10.2 to 10.6.

• 1. Chemical stability

Stable under recommended conditions of storage.

• 1. Possibility of hazardous reactions

Polymerization is not expected to occur.

• 1. Conditions to avoid

Avoid heat, sparks, open flames and other ignition sources.

• 1. Incompatible materials

May react vigorously with oxidising agents (e.g. hypochlorites). May react with some plastics, particularly styrene, acrylonitrile, and acrylonitrile-butadiene- styrene based plastics, rubber and coatings.

• 1. Hazardous decomposition products

May evolve toxic gases (carbon oxides, hydrogen chloride, phosgene, hydrocarbons) when heated to decomposition.

TOXICOLOGICAL INFORMATION

• 1. Information on toxicological effects

Acute toxicity

Based on available data, the classification criteria are not met.

Information available for the ingredients:

Ingredient	Oral LD50	Dermal LD50	Inhalation LC50
PARA-DICHLOROBENZENE	> 2000 mg/kg (rat)	> 2000 mg/kg (rabbit)	12 g/m³ (mammal)

Skin Eye

Sensitisation Mutagenicity Carcinogenicity

Reproductive

STOT – single exposure

STOT – repeated exposure

Aspiration

Contact may result in irritation, redness, pain and rash. Contact may result in irritation, lacrimation, pain and redness. Not classified as causing skin or respiratory sensitisation.

Not classified as a mutagen.

Suspected of causing cancer. Para-Dichlorobenzene is classified as possibly carcinogenic to humans (IARC Group 2B).

Not classified as a reproductive toxin.

Not classified as causing organ damage from single exposure. Not classified as causing organ damage from repeated exposure. Not classified as causing aspiration.

ECOLOGICAL INFORMATION

• 1. Toxicity

Very toxic to aquatic life with long lasting effects.

• 1. Persistence and degradability

This product is biodegradable.

• 1. Bioaccumulative potential

Para-dichlorobenzene is not considered as bioaccumulative.

• 1. Mobility in soil

No information provided.

• 1. Other adverse effects

It is possible that 1,4-dichlorobenzene will be slowly biodegraded in soil under aerobic conditions. Removal from water will be mainly by volatilisation (half life 4.3 hours from a model rive). Adsorption to sediment will be a major environmental fate process based upon extensive monitoring data. Analysis of Lake Ontario sediment cores has indicated the presence and persistence of p-dichlorobenzene since 1940.

DISPOSAL CONSIDERATIONS

• 1. Waste treatment methods

Waste disposal Legislation

Reuse where possible. No special precautions are normally required when handling this product. Dispose of in accordance with relevant local legislation.

TRANSPORT INFORMATION

NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA

	LAND TRANSPORT (ADG)	SEA TRANSPORT (IMDG / IMO)	AIR TRANSPORT (IATA / ICAO)
14.1 UN Number	None allocated.	None allocated.	None allocated.
14.2 Proper Shipping Name	None allocated.	None allocated.	None allocated.
14.3 Transport hazard class	None allocated.	None allocated.	None allocated.
14.4 Packing Group	None allocated.	None allocated.	None allocated.

• 1. Environmental hazards

Marine Pollutant.

• 1. Special precautions for user

Hazchem code Other information

None allocated.

The environmentally hazardous substance mark is not required when transported in packages of less than 5 kg/L (UN Model Regulations: Special Provision 375; IATA: Special Provision A197; IMDG: Special Provision 969) or less than 500 kg/L by Australian Road and Rail.

REGULATORY INFORMATION

• 1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Poison schedule Classifications

Inventory listings

Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).

Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification and Labelling of Chemicals.

AUSTRALIA: AIIC (Australian Inventory of Industrial Chemicals)

All components are listed on AIIC, or are exempt.

OTHER INFORMATION

Additional information

Abbreviations

EXPOSURE STANDARDS – TIME WEIGHTED AVERAGES: Exposure standards are established on the premise of an 8 hour work period of normal intensity, under normal climatic conditions and where a 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In the following circumstances, exposure standards must be reduced: Strenuous work conditions; hot, humid climates; high altitude conditions; extended shifts (which increase the exposure period and shorten the period of recuperation).

RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken. Remember that some respirators may be extremely uncomfortable when used for long periods. The use of air powered or air supplied respirators should be considered where prolonged or repeated use is necessary.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:

The recommendation for protective equipment contained within this report is provided as a guide only. Factors such as form of product, method of application, working environment, quantity used, product concentration and the availability of engineering controls should be considered before final selection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:

It should be noted that the effects from exposure to this product will depend on several factors including: form of product; frequency and duration of use; quantity used; effectiveness of control measures; protective equipment used and method of application. Given that it is impractical to prepare a report which would encompass all possible scenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.

ACGIH American Conference of Governmental Industrial Hygienists

CAS # Chemical Abstract Service number – used to uniquely identify chemical compounds CNS Central Nervous System

EC No. EC No – European Community Number

EMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods)

GHS Globally Harmonized System

GTEPG Group Text Emergency Procedure Guide IARC International Agency for Research on Cancer

LC50 Lethal Concentration, 50% / Median Lethal Concentration LD50 Lethal Dose, 50% / Median Lethal Dose

mg/m³ Milligrams per Cubic Metre OEL Occupational Exposure Limit

pH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).

ppm Parts Per Million

STEL Short-Term Exposure Limit

STOT-RE Specific target organ toxicity (repeated exposure) STOT-SE Specific target organ toxicity (single exposure)

SUSMP Standard for the Uniform Scheduling of Medicines and Poisons SWA Safe Work Australia

TLV Threshold Limit Value

TWA Time Weighted Average

Report status

This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of the product and serves as their Safety Data Sheet (‘SDS’).

It is based on information concerning the product which has been provided to RMT by the manufacturer, importer or supplier or obtained from third party sources and is believed to represent the current state of knowledge as to the appropriate safety and handling precautions for the product at the time of issue. Further clarification regarding any aspect of the product should be obtained directly from the manufacturer, importer or supplier.

While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss, injury or damage (including consequential loss) which may be suffered or incurred by any person as a consequence of their reliance on the information contained in this SDS.

Prepared by

Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005

Phone: +61 8 9322 1711

Fax: +61 8 9322 1794

Email: info@rmt.com.au Web: www.rmtglobal.com

[ End of SDS ]